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The #1 Places For Astronomy are Huntsville, AL, Houston, TX, and of course Cape Canveral in Florida.
I think you meant these places are great if you're interested in the space program or NASA. Astronomy is something different. For that, the best places are Kitt Peak, Mt Hopkins, Mt Graham and Lowell Observatory, all in Arizona. Kitt Peak for one, allows visitors during daylight hours. Also, there is a famous observatory in Hawaii (a little farther afield) and there is the fascinating VLA on the Plains of San Augustin in western New Mexico (also worth a visit). The VLA was a star in Jodie Foster's movie "Contact."